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Atmospheric oxidation is dominated by the OH radical, although Cl atoms can play an important role under certain conditions. Gas-phase inorganic chlorine (Cly) controls the Cl budget. HCl dominates Cly[1]. Atmospheric sources and levels of HCl are poorly constrained. HCl is a sticky gas and is a challenge to measure with high time resolution. Most measurements have been made using time-integrated techniques, such as mist chambers(e.g.[2]). Some recent measurements made using chemical ionization mass spectrometry, although issues with calibration and inlet transmission are common(e.g.[1,3]). A recently-available cavity-ring down instrument generates reliable measurements of HCl at 0.5Hz. Spectroscopic technique eliminates most calibration issues, while specially designed instrument reduces surface effects.

Authors

Cora J. Younga, Andrea A. Angeluccia a,TelesC. Furlania a, Alexander Moraveka a, Xuan Wangb,c, Daniel Jacobb, Rachel Y.-W. Changd, AldonaWiaceke

Publication Date

aDepartmentof Chemistry, York University, Toronto, Ontario, Canada;
bSchoolof Engineering and Applied Sciences, Harvard University, Boston, Massachusetts, US;
cSchoolof Energy and Environment, City University of Hong Kong, Hong Kong, China;
dDepartmentof Physics and Atmospheric Science, Dalhousie University, Halifax, Nova Scotia, Canada;
eDepartmentof Environmental Science, St. Mary’s University, Halifax, Nova Scotia, Canada