The Neogene Guantao formation in the Beitang sag in the Bohai Bay Basin (BBB) of North China, a Mesozoic–Cenozoic sedimentary basin of continental origin, has been chosen as a candidate for a pilot field test of CO₂ sequestration. Hydrogeological and geochemical investigations have been carried out to assess its suitability, taking advantage of many existing geothermal wells…

Variations of stable water isotopes in water vapour have become measurable at a measurement frequency of about 1 Hz in recent years using novel laser spectroscopic techniques. This enables us to perform continuous measurements for process-based investigations of the atmospheric water cycle at the time scales relevant for synoptic meteorology. An important prerequisite for the interpretation…

The goal of this study is to determine how H₂O and HDO measurements in water vapor can be used to detect and diagnose biases in the representation of processes controlling tropospheric humidity in atmospheric general circulation models (GCMs). We analyze a large number of isotopic data sets (four satellite, sixteen ground-based remote…

Soil and vadose zone profiles are used as an archive of changes in groundwater recharge and water quality following changes in land use in an area of the Loess Plateau of China. A typical rain-fed loess-terrace agriculture region in Hequan, Guyuan, is taken as an example, and multiple tracers (chloride mass balance, stable isotopes, tritium and water chemistry) are used to examine…

The lapse rate of water isotopes is used in the study of the hydrologic cycle as well as in the estimation of uplift of the Tibetan Plateau. The greater elevation contrast in the southern Himalayas allows for a detailed discussion about this lapse rate. We analyze variations of δ ¹⁸O in precipitation and river water between 1320 m and 6700 m…

Attributing observed CO₂ variations to human or natural cause is critical to deducing and tracking emissions from observations. We have used in situ CO₂, CO, and planetary boundary layer height (PBLH) measurements recorded during the CalNex-LA (CARB et al., 2008) ground campaign of 15 May–15 June 2010, in Pasadena, CA, to deduce the diurnally varying anthropogenic…

his study presents observations of atmospheric boundary layer CO₂ mole fraction from a nine-tower regional network deployed during the North American Carbon Program's Mid-Continent Intensive (MCI) during 2007–2009. The MCI region is largely agricultural, with well-documented carbon exchange available via agricultural inventories. By…

The Carbonaceous Aerosols and Radiative Effects Study (CARES) took place in the Sacramento Valley of California in summer 2010. We present results obtained at Cool, CA, the T1 site of the project (~40 km downwind of urban emissions from Sacramento), where we deployed an Aerodyne high resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) in parallel with complementary…

The multispecies analysis of daily air samples collected at the NOAA BoulderAtmospheric Observatory (BAO) in Weld County in northeastern Colorado since 2007shows highly correlated alkane enhancements caused by a regionally distributed mixof sources in the Denver-Julesburg Basin. To further characterize the emissions of methaneand non-methane hydrocarbons (propane, n-butane, i-pentane, n-…

Purpose  

The impact of CO₂ urban plume in a rural area was investigated by concentrations recorded near surface.

Methods  

CO₂ dry concentrations at three levels near surface were recorded for about 8 months at a rural site. Daily cycles were obtained and directional analysis was made with…

Gravel excavation often bears conflicts with the use of drinking water as under-water-table mining can directly impact groundwater quality downstream of the open gravel pit lake due to exposure of the groundwater aquifer to the atmosphere and to human activities. To assess this potential impact of GPLs on groundwater, we assessed the mass balance for nitrate (NO₃…

There is a close relationship between surface water and groundwater in semi-arid and arid areas of China, and thus researching on the interactions of them is of importance for reasonable water resources development. This paper took Bulang River basin as case study, analysis and discussion were conducted to water chemistry and isotopes tests results of water samples. The results show that…

The repeatability, reproducibility and accuracy of the direct measurement of δ(D) and δ(18O) isotopes inwater samples were evaluated using Cavity Ring-Down Spectrometry, and values comparable with the Isotopic Ratio Mass Spectrometry were obtained. Memory effect correction was negligible after five successive injections, and the time for each sample analysis was approximately 70 minutes.…

Stable carbon and oxygen isotopic compositions (_13C and _18O) of benthicforaminiferal carbonate shells have been used to reconstruct past bottom water environments.However, the details of factors controlling the isotopic disequilibrium be-5 tween the shells and the surrounding bottom seawater (the vital effect) are still ambiguous.In this study, we analyzed…

Hydrogen isotope ratios in lipids derived from mangroves have the potential to be used for paleohydrologic reconstructions and could serve as a much needed tool for establishing past climate variability in the tropics. We assessed the effect of salinity on the apparent fractionation factor, α_a, between mangrove derived n-alkanes and their source…

Isotope records of atmospheric CH₄ can be used to infer changes in the biochemistry of CH₄. One factor limiting quantitative estimates of changes in the biogeochemistry of CH₄ are the uncertainties of the isotope measurements due to the lack of a unique isotope reference gas, certified for ¹³C-CH₄ or ² 5 H-CH₄. We…

Tunable diode laser absorption (TDL) and cavity ring-down spectroscopic (CRDS) sensors for atmospheric  carbon dioxide were co-deployed during summer and fall of 2010 in field and laboratory conditions at Los Alamos National Laboratory. Both sensors were characterized for accuracy and precision for ambient carbon dioxide measurements at ground level and compared using both laboratory…

The experiment was conducted at twelve grazing plots denoting four treatments defined along a grazing gradient with three replications: non-grazing (0 sheep/ha, NG), light grazing (0.75 sheep/ha, LG), moderate grazing (1.50 sheep/ha, MG) and heavy grazing (2.25 sheep/ha, HG). Using an automatic cavity ring-down spectrophotometer, we measured CH₄ fluxes from March 1 to April 29 in…

Questions of mobility, settlement pattern, and their relation to economic organization and resource use are central to ongoing work in central-western Argentina. Here we analyze geographic patterns in the distribution of 178 human bone carbonate δ¹⁸O samples, 46 human tooth enamel carbonate δ¹⁸O samples, and 48 water δ^18…

In preparation for the routine deployment of the Earth Networks greenhouse gas monitoring network, we have designed and tested a simple method for drying ambient airto below 0.2 % mole fraction H2O using a Nafion dryer. The inlet was designed for usewith a Picarro model G2301 cavity ring down spectrometer (CRDS) CO2/CH45 /H2O analyzer. The analyzer measures water vapor mixing ratio at the…

This article reports the first application of coupled total organic carbon cavity ring-down spectroscopy (TOC-CRDS) for the analysis of the δ¹³C signature of dissolved organic carbon (DOC) in freshwater samples. DOC represents a major, dynamic component of the global carbon cycle. The export of DOC from soils into rivers and groundwaters may be highly climate…

Within the project MUSICA (MUlti-platform remote Sensing of Isotopologues for investigating the Cycle of Atmospheric water), long-term tropospheric water vapour isotopologues data records are provided for ten globally distributed ground-based mid-infrared remote sensing stations of the NDACC (Network for the Detection of Atmospheric Composition Change). We present…