The regulation of Earth’s climate and its ability to sustain life are critically linked to water as it exists in all three of its phases (gas, liquid, and solid). Earth’s water cycle, its movement between the hydrosphere, biosphere, and the atmosphere, and how it undergoes phase changes, is incredibly complex. While we continue to gain insight into the water cycle, there remains…

Cavity Ring-Down spectroscopy is becoming a gold standard for atmospheric monitoring. High sensitivity and precision coupled with low drift characteristics ensure optimal operation even in remote field stations or on aircraft and ships. However, current platforms have been limited to two or three species simultaneous observation. Research and development at Picarro have been focused on…

Hydrothermal fluids from two vent sites along the East Scotia Ridge, E2 and E9, were analyzed for their hydrogen and oxygen isotopic values using a Picarro L1115-i CRDS. The fluids display varying salinity, sulfate and hydrogen sulfide content. None of the samples analyzed in this work showed any signs of spectroscopic interference. Isotopic values of the fluids were combined with…

The world’s first continuous flow isotopic TIC/DOC-CRDS measurements are reported here with remarkable achieved precisions. A measurement precision of the isotopic ratio in the range of 0.2 ‰ to 0.4 ‰ was achieved in minutes of measurement time. Such precision readily distinguishes the isotopic DIC and DOC signatures from a set of three different streamwater samples collected from various…

The recent development of a field deployable water isotope analyzer using CRDS technology was used to directly measure the vapor isotopes in real time and at multiple heights above the crop canopy. This technique was coupled with additional samples gathered using conventional techniques and a new xylem water extracting apparatus developed by the IAEA.

In a paper published by the Integrated Carbon Observation System (ICOS), the drift performance of 47 Picarro analyzers of 3 different generations were compared (Yver Kowket al, Atmos. Meas. Tech. Discuss., 8, 4219–4272, 2015). The results show that methane drift (the minimum of the Allan standard deviation) was much better in first-generation G1000 analyzers.

High-salinity waters such as Seawater poses an operational and maintenance challenge to the measurements of water stable isotopes via Cavity Ring-Down Spectroscopy. As liquid samples are evaporated in the vaporizer peripheral before being sent to the CRDS analyzer, salt precipitates accumulate in the vaporizer chamber. As a result, the sample-to-sample memory performance degrades over time…

Soil flux chamber measurements are a key tool for determining production and sequestration of direct and indirect greenhouse gases. The Picarro G2508 Cavity Ring-down Spectrometer radically simplifies soil flux analyses by providing simultaneous measurements of five gases: CO2, CH4, N2O, NH3, and H2O, and by ready field deployment. The Picarro Soil Flux Software (SFP) …

With a global warming potential of nearly 300, N2O is a critically important greenhouse gas, contributing about 5 % of the US total GHG  emissions.  Agriculture soil management practices are the dominant source of anthropogenic N2O emissions, contributing nearly 75 % of US N2O emissions.  In urban areas, vehicle tailpipe emissions and waste water treatment plants are…

The necessity for constant monitoring of greenhouse gases (GHGs) is clearly evident now more than ever. Moreover, interpreting and understanding the processes that dictate the production and consumption of these gases will allow for proper management of GHGs in order to mitigate its detrimental climate effects. Presence of oxygen, or lack of it, is the driving force for determining pathways…

One mustn’t look too far to find a story about natural gas production - whether from the perspective that it will transform the global economy or drive the climate past the point of no return. Whether you’re for gas or against it, the only chance we have to make clearheaded decisions about the issue is through credible measurements and complete transparency.

Without question, the…

Natural gas will not live up to its promise without the vital support of a society focused on transparency.

One mustn’t look too far to find a story about natural gas production - whether from the perspective that it will transform the global economy or drive the climate past the point of no return. Whether you’re for gas or against it, the only chance we have to make…

Friday’s post with details of Michael Woelk’s Energy Innovation Pioneer Showcase Presentation tomorrow at CERAWeek 2013 mentioned that we would be announcing a major addition to our Surveyor™ mobile, real-time geo-informatics platform…

A Picarro Surveyor™ for natural gas leaks is in Houston, TX USA this week (March 4 to 8) for test drives. Please text or call Chris Vale at 404.734.1170…

This evening at 8:00 P.M. PSD, there is an hour long KQED (Public Radio for Northern California) radio program related to hydraulic fracturing (Wednesday, March 13^th ). The program presents a conversation with Fred Krupp, president of the Environmental Defense Fund; and Rhonda Zygocki, vice president…

Stephanie Paige Ogburn of ClimateWire has written an in-depth 3-part series on natural gas that makes a compelling case for accurately measuring leaks from production to delivery. While we cooperated with Stephanie, and are flattered that…

During a visit with the EPA in Washington DC just over a month ago, Michael Woelk, Picarro CEO, had an opportunity to set down with a diverse group of media: Platts Energy Week, ClimateWire and The New York Times. Mike was impressed with the research the…

The identification and quantification of methane emissions from natural gas production has become increasingly important owing to the increase in the natural gas component of the energy sector. An instrumented aircraft platform was used to identify large sources of methane and quantify emission rates in southwestern PA in June 2012. A large regional flux, 2.0–14 g CH₄ s^−1…

Atmospheric concentration measurements are used to adjust the daily to monthly budget of CO₂ emissions from the AirParif inventory of the Paris agglomeration. We use 5 atmospheric monitoring sites including one at the top of the Eiffel tower. The atmospheric inversion is based on a Bayesian approach, and relies on an atmospheric transport model with a spatial resolution of 2…

Weekly samples from surface waters, springs, soil water and rainfall were collected in a 76.9 km2 mountain rain forest catchment and its tributaries in southern Ecuador. Time series of the stable water isotopes δ18O and δ2H were used to calculate mean transit times (MTTs) and the transit time distribution functions (TTDs) solving the convolution…

We present CH₄ concentration [CH₄] and the partial pressure of CO₂ (pCO₂) in bulk sea ice from subarctic, land-fast sea ice in the Kapisillit fjord, Greenland. The bulk ice [CH₄] ranged from 1.8 to 12.1 nmol L⁻¹, which corresponds to a partial pressure range of 3 to 28 ppmv. This is markedly higher than the…

The addition of pyrogenic carbon (C) in the soil is considered a potential strategy to achieve direct C sequestration and potential reduction of non-CO₂ greenhouse gas emissions. In this paper, we investigated the long term effects of charcoal addition on C sequestration and soil physico-chemical properties by studying a series of abandoned charcoal hearths in…

Extra-tropical cyclones, such as 2012 Superstorm Sandy, pose a significant climatic threat to the northeastern United Sates, yet prediction of hydrologic and thermodynamic processes within such systems is complicated by their interaction with mid-latitude water patterns as they move poleward. Fortunately, the evolution of these systems is also recorded in the stable isotope ratios of storm-…

Accumulation is a key parameter governing the mass balance of the Greenland ice sheet. Several studies have documented the spatial variability of accumulation over wide spatial scales, primarily using point data, remote sensing or modeling. Direct measurements of spatially extensive, detailed profiles of accumulation in Greenland, however, are rare. We used 400 MHz ground-penetrating radar…

The groundwater flow systems and chemistry in the deep part of the coastal area of Japan have attracted attention over recent decades due to government projects such as geological disposal of radioactive waste. However, the continuous groundwater flow system moving from the shallow to deep parts of the sedimentary soft rock has not yet been characterized. Therefore, the Cl^–, δD…

The destructive effects of sulfate attack on concrete structures are well known, but the reaction paths and mechanisms that cause the deterioration are still under debate. The aim of this study is to contribute to a deeper understanding on investigating concrete damage by introducing a novel and promising multi proxy approach method. The methodology comprises advanced…

RATIONALE:

Low-budget rain collectors for water isotope analysis, such as the 'ball-in-funnel type collector' (BiFC), are widely used in studies on stable water isotopes of rain. To date, however, an experimental quality assessment of such devices in relation to climatic factors does not exist.

METHODS:

We used Cavity Ring-Down…

Development of cavity ring-down spectroscopy (CRDS) has enabled real-time monitoring of carbon stable isotope ratios of carbon dioxide and methane in air. Here we demonstrate that CRDS can be adapted to assess aquatic carbon cycling processes from microbial to ecosystem scales. We first measured in situ isotopologue concentrations of dissolved CO₂ (¹²CO_2…

Changes in atmospheric circulation over the past five decades have enhanced the wind-driven inflow of warm ocean water onto the Antarctic continental shelf, where it melts ice shelves from below. Atmospheric circulation changes have also caused rapid warming…

Scarcity of mercury species records in the Southern Hemisphere is a critical weak point for the development of appropriate modeling and regulation scenarios. Under the framework of the “Global Mercury Observation System” (GMOS) project, a monitoring station has been set up on Amsterdam Island (37_480 S, 77_340 5 E) in the remote southern Indian Ocean. For the first time in the Southern…